Nano Nickel Powder

Company: 
Hefei Quantum Quelle Nano Science & Technology Co., Ltd.
 
Material: Nickel
Specification:

Material Safety Data Sheet
Nano Nickel Powder


1. Product and Company Identification
PRODUCT NAME: Nicke Powder
SYNONYMS: Ni
MANUFACTURER: HeFei Quantum Quelle Nano Science and Technology Co., Ltd
ADDRESS: 35#New Station Industry Park,
Hefei Anhui
EMERGENCY PHONE
OTHER CALLS: (86)551-4280850
FAX: (86)551-4280321


2. Composition/Information on Ingredients
Ingredient CAS No Percent
Nickel 7440-02-0 99.5%
CHEMICAL NAME: Nickle
CHEMICAL FAMILY: Metal
CHEMICAL FORMULA: Ni


3. Hazards Identification
Emergency Overview
Harmful. nonflammable(USA)
Possible Carcinogen (USA) Calif.Prop 65 Carcinogen
Limited evidence of a carcinogenic effect. May cause sensitization by skin contact
Target organ(s): Nasal cavities, lungs, skin
Safety Data
HMIS Ratings: Health=3, Flammability=0, Reactivity=0
Lab Protective Equip: Goggles; Lab coat
Storage Color Code: sepia brown
Potential Health Effects
Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and
upper respiratory tract..May cause asthmatic attacks due to allergic sensitization of the
respiratory tract. Inhalation of fumes may cause metal fume fever, which is characterized by
flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain
and increased white blood cell count.May cause loss of smell.
Ingestion:May be harmful if swallowed. May cause gastrointestinal irritation with nausea,
vomiting and diarrhea.May cause tremors and convulsions. Ingestion of large amounts may
cause gastroenteritis.
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Nickel PowderMSDS 2
Skin Contact: May cause skin irritation and possible burns. Causes “nickel itch” which is a
dermatitis resulting from sensitization to nickel, which is characterized by skin eruptions,
followed by discrete ulcers that may discharge and become crusted, or by eczema. May cause
sensitization by skin contact
Eye Contact: May cause eye irritation.Causes redness and pain. May cause chemical
conjunctivitis and corneal damage.
Chronic Exposure: This product contains a component that has been reported to be possibly
carcinogenic based on its IARC, ACGIH, NTP or EPA classification.
Aggravation of Pre-existing Conditions: Skin contact can cause an allergic skin rash in
previously sensitized individuals.


4. First AidMeasures
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Seek medical attention if cough or other symptoms appear
Ingestion: Do not induce vomiting. Wash out mouth with water and give 2-4 cups of milk or
water. Never give anything by mouth to an unconscious person. Seek medical attention
immediately.
Skin Contact: Flush with copious amounts of soap and water for at least 15 minutes. Remove
contaminated clothing and shoes. Seek medical attention if irritation develops or persists. Wash
clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Flush with copious amounts of water for at least 15 minutes, occasionally lifting
lower and upper eyelids. Seek medical attention immediately.


5. Fire FightingMeasures
Fire: nonflammable particle. Any very finely divided particles (ultra-fine powder) may burn in air
when exposed to heat or flame.
Pyrophoric/Autoignition: No
Explosion: This material presents no explosive hazard.
Fire Extinguishing Media: Dry chemical powder or sand – do not use water, carbon dioxide or
foam.Dousing metallic fires with water may generate hydrogen gas, an extremely dangerous
explosion hazard,particularly if fire is in a confined environment..
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full facepiece operated in the pressure demand or
other positive pressure mode.
Specific Hazard(s): Emits toxic fumes under fire conditions.
NFPA Ratings: Health: 3, Flammability: 0, Reactivity: 0


6. Accidental ReleaseMeasures
In case of a leak or spill, evacuate area, shut off all sources of ignition and use nonsparking
tools. Wear NIOSH approved respirator, rubber boots, and heavy rubber gloves. Wear
disposable coveralls and discard after use. Sweep up the spill, place in a bag and hold for
waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pick-up is
complete.


7. Handling and Storage
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Nickel PowderMSDS 3
Do not inhale powder. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated
exposure. Wash thoroughly after handling. Keep in a tightly closed container, away from heat,
sparks, electrostatic discharge and open flame. Store in a cool, dry place. Isolate from
incompatible substances. Containers of this material may be hazardous when empty since they
retain product residues (dust,solids); observe all warnings and precautions listed for the product


8. Exposure Controls, Personal Protection
Airborne Exposure Limits:
- OSHA Permissible Exposure Limit (PEL) 1 mg/m3 (TWA)
- ACGIH Threshold Limit Value (TLV) 1.5 mg/m3 (TWA), inhalable fraction
- NIOSH Recommended Exposure Limit (REL) 0.015mg/m3 (TWA)
- NIOSH Immediately Dangerous to Life or Health Concentration (IDLH) 10 mg/m3 (as Ni)
Ventilation System: A system of local and/or general exhaust is recommended to keep
employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally
preferred because it can control the emission of the contaminant at its source, preventing
dispersion of it into the general work area.
Respiratory Protection Equipment: Respirators may be necessary when engineering and
administrative controls do not adequately prevent exposures. Currently, there are no specific
exposure limits for airborne exposures to engineered nano particles although occupational
exposure limits exist for larger particles of similar chemical composition. The decision to use
respiratory protection should be based on professional judgment that takes into account toxicity
information, exposure measurement data, and frequency and likelihood of the worker’s
exposure. Preliminary evidence shows that for respiration filtration media there is no deviation
from the classical single-fiber theory for particulates as small as 2.5 nm in diameter. While this
evidence needs confirmation, NIOSH certified respirators will be useful for protecting workers
from nano particles inhalation when properly selected and fit tested as part of a complete
respiratory protection program. Use NIOSH approved positive flow mask if dust becomes
airborne. Try to avoid creating dust conditions.
Skin Protection: Wear impervious protective clothing including boots, gloves, lab coat, apron or
coveralls, as appropriate, to prevent skin contact. Wash thoroughly after handling. Maintain
quick-drench facilities in work area.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing
of solution is possible. Maintain eye wash fountain in work area.


9. Physical and Chemical Properties
Appearance: Sepia brown powder with an average particle size of 20 – 300 nanometers.
Odor: Weak odor
Solubility: Insoluble in water
Theoretical Density: 8.90 g/cm3
MolecularWeight: 58.71 AMU
PH: Not available
Melting Point: 1453 ℃ (2647F)
Boiling Point: 2732 ℃ (4950F)
Vapor Density (Air=1): Not available
Vapor Pressure: 1mm Hg at 1810C
Evaporation Rate: Not available
Viscosity: Not applicable
Decomposition Temperature: Not available
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Nickel PowderMSDS 4


10. Stability and Reactivity
Chemical Stability: Stable under ordinary conditions of use and storage. Avoid exposure to
moisture.
Hazardous Decomposition Products: Nickel oxides, carbon monoxide, carbon dioxide, toxic and
highly flammable nickel carbonyl.
Hazardous Polymerization: Will not occur.
Incompatibilities: Nickel is incompatible with acids, oxidizing agents, organic solvents, and
sulfur.
Conditions to Avoid: Ignition sources, excess heat, dust generation, incompatibles and
exposure to moisture.


11. Toxicological Information
Route of Exposure
Skin Contact: Prolonged and intimate contact with metallic nickel may cause irritation to the
skin and nickel sensitivity which may result in allergic skin rashes.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and
upper respiratory tract.
Ingestion: May be harmful if swallowed
NTP Known Carcinogen: Yes
NTP Anticipated Carcinogen: Yes
IARC Category: Group 1 carcinogen (listed as Nickel compounds)
California Carcinogen: Yes


12. Ecological Information
Environmental: No information reported.
Environmental Toxicity: No data available.


13. Disposal Considerations
Contact a licensed professional waste disposal service to dispose of this material. Processing,
use or contamination of this product may change the waste management options. Observe
all Federal, State, and Local environmental regulations.


14. Transport Information
Explosives: The product presents no explosive hazard
Flammability: The product does not belong to flammable substance


15. Regulatory Information
Ingredient --Chemical Inventory Status – Part 1--
TSCA EC Japan Australia
Nickel (7440-02-0) yes see below not avail No
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Nickel PowderMSDS 5
Chemical Inventory Status – Part 2-
-Canada--
Ingredient Korea DSL NDSL Phil.
Nickel (7440-02-0) not avail Yes No not avail
Federal, State & International Regulations – Part 1-
--SARA 302-- ------SARA 313-----
Ingredient RQ TPQ List Chemical Catg.
Nickel (7440-02-0) No Yes
Federal, State & International Regulations – Part 2 -
-RCRA- -TSCAIngredient
CERCLA 261.33 8 (d)
Nickel (7440-02-0) 100 lb. final RQ*
*no reporting of releases of this hazardous substance is required.
Chemical Weapons Convention: No
TSCA 12(b): Not listed.
CDTA: No
SARA 311/312: Acute: Yes, Chronic: Yes, Flammable: Yes, Pressure: No, Reactivity: No Clean
Air Act: Hazardous pollutant; does not contain any Class 1 or Class 2 Ozone depletors. Clean
Water Act: Priority pollutant, toxic pollutant.
European/International Regulations: European labeling in accordance with EC Directives.
Hazard Symbols: XNF
Risk Phrases: R40 Limited evidence of a carcinogenic effect. R43 May cause sensitization by
skin contact.
Safety Phrases:
S16 Keep away from sources of ignition – No smoking.
S22 Do not breathe dust.
S36 Wear suitable protective clothing.
Poison Schedule: None allocated.
Canada - WHMIS: classification B4 and D2A
Canada Ingredient Disclosure List: Yes


16. Other Information
Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED or INHALED. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE NASAL or LUNG
DAMAGE. MAY CAUSE ALLERGIC SKIN or RESPIRATORY REACTION. CANCER
HAZARD.
Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Avoid breathing dust or vapors. Keep container closed. Use only with adequate ventilation
Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact,
immediately flush eyes or skin with plenty of water for at least 15 minutes.
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Nickel PowderMSDS 6
Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, seek
medical attention.
Product Use: Laboratory Reagent.
Disclaimer:
HeFei Quantum Quelle Nano Science and Technology Co., Ltd believes that the information in
this Material Safety Data Sheet is accurate and represents the best and most current
information available to us. However, we make no warranty of merchantability or any other
warranty, expressed or implied, with respect to such information, and we assume no liability
resulting from its use or misuse. Users should make their own investigations to determine the
suitability of the information for their particular purposes. In no way shall We be liable for any
claims, losses or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if the company has been
advised of the possibility of such damages.


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